The magnetic Mobius strip: Synthesis, structure, and magnetic studies of odd-numbered antiferromagnetically coupled wheels

被引：106

作者：

Cador, O

Gatteschi, D

Sessoli, R

Larsen, FK

Overgaard, J

Barra, AL

Teat, SJ

Timco, GA

Winpenny, REP

机构：

[1] Univ Florence, Dipartimento Chim, Lab Magnetismo Mol, I-50019 Sesto Fiorentino, Italy

[2] Univ Florence, INSTM, I-50019 Sesto Fiorentino, Italy

[3] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

[4] Univ Aarhus, Dept Chem, Aarhus, Denmark

[5] CNRS, Lab Champs Magnet Intenses, F-38042 Grenoble 9, France

[6] CCLRC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 39期

关键词：

cage compounds; chromium; heterometallic complexes; magnetic properties; spin frustration;

D O I：

10.1002/anie.200460211

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Understanding frustration: The control of structure through the choice of the template has allowed the synthesis of nonanuclear metal wheels that contain {Cr8Ni} or {Cr7(VO)2} cores. Magnetic studies (see picture) of one of these wheels shows that it behaves as a magnetic Möbius strip. These are the first detailed magnetic studies of an odd-numbered ring larger than trinuclear and should help in the understanding of spin-frustrated systems.

引用

页码：5196 / 5200

页数：5

共 18 条

[1]

[Anonymous], 1998, PROGRAMS CRYSTAL STR

[2]

[Anonymous], 1996, ANGEW CHEM, V108, P1987

[3] Neutron diffraction evidence for an antiferromagnetic ordering in the CMR manganites Pr0.7Ca0.3-xSrxMnO3 [J].