Dye adsorption by prehydrolysed beech sawdust in batch and fixed-bed systems

被引:137
作者
Batzias, F. A. [1 ]
Sidiras, D. K. [1 ]
机构
[1] Univ Piraeus, Dept Ind Management & Technol, Lab Simulat Ind Proc, GR-18534 Piraeus, Greece
关键词
basic dyes; adsorption; sawdust; wood; prehydrolysis; column;
D O I
10.1016/j.biortech.2006.05.020
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The batch and column kinetics of methylene blue and red basic 22 adsorption on mild acid-hydrolysed beech sawdust were investigated, using untreated beech sawdust as control, in order to explore its potential use as a low cost adsorbent for wastewater dye removal. The adsorption capacities, estimated according to Freundlich's model, and the adsorption capacity coefficient values, determined using the Bohart and Adams' bed depth service model, indicated that prehydrolysis enhances the adsorption properties of the original material. This enhancement can possibly be attributed to (a) the removal of the hemicelluloses during sulphuric acid treatment, resulting in the 'opening' of the lignocellulosic matrix's structure and the increasing of the BET surface area and (b) the activation of the material's surface owing to an increase in the number of dye binding sites. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1208 / 1217
页数:10
相关论文
共 43 条
[1]   COLOR REMOVAL VIA ADSORPTION ON WOOD SHAVING [J].
ABOELELA, SI ;
ELDIB, MA .
SCIENCE OF THE TOTAL ENVIRONMENT, 1987, 66 :269-273
[2]   Biosorption of reactive dyes by dried activated sludge: equilibrium and kinetic modelling [J].
Aksu, Z .
BIOCHEMICAL ENGINEERING JOURNAL, 2001, 7 (01) :79-84
[3]   Comparison of optimised isotherm models for basic dye adsorption by kudzu [J].
Allen, SJ ;
Gan, Q ;
Matthews, R ;
Johnson, PA .
BIORESOURCE TECHNOLOGY, 2003, 88 (02) :143-152
[4]   Use of cellulose-based wastes for adsorption of dyes from aqueous solutions [J].
Annadurai, G ;
Juang, RS ;
Lee, DJ .
JOURNAL OF HAZARDOUS MATERIALS, 2002, 92 (03) :263-274
[5]   Adsorption of methylene blue from an aqueous solution on to activated carbons from palm-tree cobs [J].
Avom, J ;
Mbadcam, JK ;
Noubactep, C ;
Germain, P .
CARBON, 1997, 35 (03) :365-369
[6]  
Batzias FA, 2001, INT SER PROG WAT RES, V3, P143
[7]   Some aspects of the behavior of charcoal with respect to chlorine. [J].
Bohart, GS ;
Adams, EQ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1920, 42 :523-544
[8]   Sorption isotherms and behaviour of direct dyes on lyocell fibres [J].
Carrillo, F ;
Lis, MJ ;
Valldeperas, J .
DYES AND PIGMENTS, 2002, 53 (02) :129-136
[9]   Reuse of activated sludge biomass: II. The rate processes for the adsorption of basic dyes on biomass [J].
Chu, HC ;
Chen, KM .
PROCESS BIOCHEMISTRY, 2002, 37 (10) :1129-1134
[10]  
CLARK RM, 1987, J AM WATER WORKS ASS, V79, P33