Liquid-mediated metathetical synthesis of binary and ternary transition-metal pnictides

被引：13

作者：

Carmalt, CJ ^{[1
]}

Morrison, DE ^{[1
]}

Parkin, IP ^{[1
]}

机构：

[1] UCL, Christopher Ingold Labs, Dept Chem, London WC1H 0AJ, England

来源：

POLYHEDRON | 2000年 / 19卷 / 07期

关键词：

antimonides; arsenides; metathesis; phosphides;

D O I：

10.1016/S0277-5387(00)00323-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nickel and cobalt pnictides have been synthesised using a liquid-mediated metathetical reaction of transition-metal dihalides with the appropriate sodium pnictide Na(3)E (E=P, As, Sb) in refluxing toluene for 48 h. Binary and ternary compounds have been prepared. Products were analysed by powder X-ray diffraction, scanning electron microscopy, energy dispersive analysis by X-rays, FT-IR, Raman and vibrating sample magnetometry. (C) 2000 Elsevier Science Ltd All rights reserved.

引用

页码：829 / 833

页数：5

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