Novel asymmetrically substituted metallophthalocyanines for nonlinear optics

被引:14
作者
Tian, M
Wada, T
Kimura, H
Sasabe, H
机构
[1] Frontier Research Program, Inst. of Phys. and Chemical Research, Wako, Saitama 351-01
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1997年 / 294卷
关键词
D O I
10.1080/10587259708032299
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Highly soluble asymmetrically substituted vanadylphthalocyanines with dodecakis(2,2,2-trifluoroethoxy) groups as a donor and a mono-nitro group as an acceptor substituent, or with extended exocyclic conjugation, have been synthesized and characterized. Their linear and nonlinear optical properties were studied. Second harmonic generation of thin films of poly(methyl methacrylate) doped with these vanadylphthalocyanines was observed after electric poling at a fundamental wavelength of 1.064 mu m.
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收藏
页码:271 / 274
页数:4
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