Photocatalytic syntheses of azoxybenzene by visible light irradiation of silica-coated cadmium sulfide nanocomposites

被引:74
作者
Pal, Bonamali
Torimoto, Tsukasa
Okazaki, Ken-ichi
Ohtani, Bunsho
机构
[1] JST, PRESTO, Kawaguchi 3320012, Japan
[2] Nagoya Univ, Grad Sch Engn, Dept Crystalline Mat Sci, Chikusa Ku, Nagoya, Aichi 4648603, Japan
[3] Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0010021, Japan
关键词
D O I
10.1039/b616178b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photoirradiation (lambda = 436 nm) of a deaerated 2-propanol aqueous solution containing nitrobenzene and rhodium-loaded silica-coated cadmium sulfide nanoparticles produced azoxybenzene with relatively high selectivity (68%), the photocatalytic activity being enhanced with a decrease in the size of the semiconductor particle core.
引用
收藏
页码:483 / 485
页数:3
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