Triangular and tetrahedral array of silver(I) ions by a novel disk-shaped tridentate ligand: Dynamic control of coordination equilibrium of the silver(I) complexes

被引：113

作者：

Hiraoka, S

Yi, T

Shiro, M

Shionoya, M ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan

[2] Rigaku Corp, Akishima, Tokyo 1968666, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 49期

关键词：

D O I：

10.1021/ja028659n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A disk-shaped tridentate ligand 1 arranges silver(I) ions in a two-dimensional triangular and a three-dimensional tetrahedral fashion in the metal-ligand ratios, 3:2 and 1:1, respectively. The resulting sandwich-type (Ag312) and tetrahedral (Ag414) architectures are in a dynamic equilibrium in solution. Copyright © 2002 American Chemical Society.

引用

页码：14510 / 14511

页数：2

共 14 条

[1]

Baxter PNW, 2000, CHEM-EUR J, V6, P4510, DOI 10.1002/1521-3765(20001215)6:24<4510::AID-CHEM4510>3.0.CO

[2]

2-P

[3]

Calama MC, 2000, ANGEW CHEM INT EDIT, V39, P755, DOI 10.1002/(SICI)1521-3773(20000218)39:4<755::AID-ANIE755>3.0.CO

[4]

2-6