A "Cyanine-Cyanine" Salt Exhibiting Photovoltaic Properties

被引:69
作者
Bouit, Pierre-Antoine [1 ,2 ]
Rauh, Daniel [3 ]
Neugebauer, Stefan [4 ]
Luis Delgado, Juan [2 ,6 ]
Di Piazza, Emmanuel [5 ]
Rigaut, Stephane [5 ]
Maury, Olivier [1 ]
Andraud, Chantal [1 ]
Dyakonov, Vladimir [3 ,4 ]
Martin, Nazario [2 ,6 ]
机构
[1] Univ Lyon, Chim Lab, Ecole Normale Super Lyon, CNRS,UMR 5182, F-69007 Lyon, France
[2] IMDEA Nanociencia, Fac Ciencias, Madrid 28049, Spain
[3] Bavarian Ctr Appl Energy Res ZAE Bayern, D-97074 Wurzburg, Germany
[4] Univ Wurzburg, D-97074 Wurzburg, Germany
[5] Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France
[6] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Organ, E-28040 Madrid, Spain
关键词
ORGANIC PHOTOVOLTAICS; SOLAR-CELLS; DYES; PERFORMANCE; DONOR;
D O I
10.1021/ol901764t
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Association between cationic and anionic heptamethine dyes led to the formation of a new organic salt (3) displaying exceptional light-harvesting properties in the NIR spectral range and having amphoteric redox character. Preliminary results of molecular bulk heterojunction solar cells based on the title compound 3 and [60]PCBM as the only active layer reveal this new dye as a promising light-harvesting material for photovoltaics.
引用
收藏
页码:4806 / 4809
页数:4
相关论文
共 21 条
  • [1] High efficiency organic photovoltaics incorporating a new family of soluble fullerene derivatives
    Backer, Scott A.
    Sivula, Kevin
    Kavulak, David F.
    Frechet, Jean M. J.
    [J]. CHEMISTRY OF MATERIALS, 2007, 19 (12) : 2927 - 2929
  • [2] Two-photon absorption at telecommunications wavelengths in a dipolar chromophore with a pyrrole auxiliary donor and thiazole auxiliary acceptor
    Beverina, L
    Fu, J
    Leclercq, A
    Zojer, E
    Pacher, P
    Barlow, S
    Van Stryland, EW
    Hagan, DJ
    Brédas, JL
    Marder, SR
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (20) : 7282 - 7283
  • [3] Stable near-infrared anionic polymethine dyes: Structure, photophysical, and redox properties
    Bouit, Pierre-Antoine
    Di Piazza, Emmanuel
    Rigaut, Stephane
    Le Guennic, Boris
    Aronica, Christophe
    Toupet, Loic
    Andraud, Chantal
    Maury, Olivier
    [J]. ORGANIC LETTERS, 2008, 10 (19) : 4159 - 4162
  • [4] Near IR nonlinear absorbing chromophores with optical limiting properties at telecommunication wavelengths
    Bouit, Pierre-Antoine
    Wetzel, Guillaume
    Berginc, Gerard
    Loiseaux, Brigitte
    Toupet, Loic
    Feneyrou, Patrick
    Bretonniere, Yann
    Kamada, Kenji
    Maury, Olivier
    Andraud, Chantal
    [J]. CHEMISTRY OF MATERIALS, 2007, 19 (22) : 5325 - 5335
  • [5] Novel water-soluble near-infrared cyanine dyes:: Synthesis, spectral properties, and use in the preparation of internally quenched fluorescent probes
    Bouteiller, Cedric
    Clave, Guillaume
    Bernardin, Aude
    Chipon, Bertrand
    Massonneau, Marc
    Renard, Pierre-Yves
    Romieu, Anthony
    [J]. BIOCONJUGATE CHEMISTRY, 2007, 18 (04) : 1303 - 1317
  • [6] On the use of cyanine dyes as low-bandgap materials in bulk heterojunction photovoltaic devices
    Castro, Fernando A.
    Faes, Antonin
    Geiger, Thomas
    Graeff, Carlos F. O.
    Nagel, Matthias
    Nueesch, Frank
    Hany, Roland
    [J]. SYNTHETIC METALS, 2006, 156 (14-15) : 973 - 978
  • [7] Enhanced cyanine solar cell performance upon oxygen doping
    Fan, Bin
    Hany, Roland
    Moser, Jacques-Edouard
    Nueesch, Frank
    [J]. ORGANIC ELECTRONICS, 2008, 9 (01) : 85 - 94
  • [8] Near-infrared-emissive polymersomes:: Self-assembled soft matter for in vivo optical imaging
    Ghoroghchian, PP
    Frail, PR
    Susumu, K
    Blessington, D
    Brannan, AK
    Bates, FS
    Chance, B
    Hammer, DA
    Therien, MJ
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2005, 102 (08) : 2922 - 2927
  • [9] Bulk heterojunction organic solar cells based on merocyanine colorants
    Kronenberg, Nils M.
    Deppisch, Manuela
    Wuerthner, Frank
    Lademann, Hans W. A.
    Deing, Kaja
    Meerholz, Klaus
    [J]. CHEMICAL COMMUNICATIONS, 2008, (48) : 6489 - 6491
  • [10] High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends
    Li, G
    Shrotriya, V
    Huang, JS
    Yao, Y
    Moriarty, T
    Emery, K
    Yang, Y
    [J]. NATURE MATERIALS, 2005, 4 (11) : 864 - 868