Laser-induced fluorescence of radicals produced in reactions of halogenated ethylenes with atomic oxygen

被引：10

作者：

Washida, N

Furubayashi, M

Imamura, T

Bridier, I

Miyoshi, A

机构：

[1] Division of Atmospheric Environment, Natl. Inst. for Environ. Studies, Tsukuba-shi, Ibaraki, 305

[2] Dept. of Chemical System Engineering, University of Tokyo, Bunkyo-ku, Tokyo 113

来源：

JOURNAL OF CHEMICAL PHYSICS | 1997年 / 107卷 / 17期

关键词：

D O I：

10.1063/1.474940

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three new laser-induced fluorescence spectra have been observed when reacting oxygen atoms with halogenated ethylenes such as CHFCF2, CF2CHCl, CH2CCl2, CH2CHCl, and CHClCHCl. These new spectra are similar to those reported previously for the vinery (CH2CHO) and CH2CFO radicals, which suggests that they can be assigned to other halogenated vinery-type radicals. Recently Williams and Fleming assigned one of these LIF spectra to the FCO radical; additional experiments have been done to address this conflicting assignment. (C) 1997 American Institute of Physics. [S0021-9606(97)03841-5].

引用

页码：6998 / 7000

页数：3

共 10 条

[1]

BRIDIER I, UNPUB

[2] Laser-induced fluorescence of the CH2CFO radical [J].