Intercalation effects in LDPE/o-montmorillonites nanocomposites

被引：63

作者：

Malucelli, Giulio

Ronchetti, Silvia

Lak, Nahal

Priola, Aldo

Dintcheva, Nadka Tzankova

La Mantia, Francesco Paolo

机构：

[1] Politecn Torino, Dipartimento Sci Mat & Ingn Chim, I-10129 Turin, Italy

[2] Politecn Torino, Local INSTM Unit, I-10129 Turin, Italy

[3] Univ Palermo, Dipartimento Ingn Chim, I-90128 Palermo, Italy

[4] Univ Palermo, Local INSTM Unit, I-90128 Palermo, Italy

来源：

EUROPEAN POLYMER JOURNAL | 2007年 / 43卷 / 02期

关键词：

LDPE nanocomposites; organo-montmorillonites; intercalation; thermal properties;

D O I：

10.1016/j.eurpolymj.2006.11.024

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 [高分子化学与物理]; 080501 [材料物理与化学]; 081704 [应用化学];

摘要：

Typical montmorillonite clays (Cloisite (R) Na(+), Cloisite (R) 3013) were modified by treatment with octadecyl ammonium chloride (ODC) and successive additions of octadecylamine (ODA). XRD analyses of the modified clays indicated an increase of the basal spacing of the (00 1) planes depending on the ODC or ODA additions. Nanocomposites were prepared by dispersing the modified clays (3% w/w concentration) in LDPE, using a Brabender mixer. XRD measurements of the obtained products indicated in some cases the achievement of intercalation effects, which were confirmed by TEM analysis. Some thermal, mechanical, dynamic-mechanical and theological properties were evaluated and correlated to the degree of intercalation. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：328 / 335

页数：8

共 16 条

[1]

Polyethylene-layered silicate nanocomposites prepared by the polymerization-filling technique:: synthesis and mechanical properties [J].