Density Enhancement of Aligned Single-Walled Carbon Nanotube Thin Films on Quartz Substrates by Sulfur-Assisted Synthesis

被引:48
作者
McNicholas, Thomas P. [1 ]
Ding, Lei [1 ]
Yuan, Dongning [1 ]
Liu, Jie [1 ]
机构
[1] Duke Univ, Dept Chem, Durham, NC 27708 USA
关键词
GROWTH; ARRAYS;
D O I
10.1021/nl901890x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The density of the aligned single-walled carbon nanotubes (SWNTs) grown on quartz substrates is an important factor for the performance of fabricated electronic devices. It was discovered that the addition of a sulfur-containing compound (thiophene) to the reaction mixture improved the density of SWNTs by a factor of 2 or more, from similar to 2-4 SWNTs/mu m to 6-8 SWNTs/mu m under similar growth conditions. It was also observed that along with the increase in nanotube density, the cleanness of the samples Improved as well. These effects were demonstrated over a large range of growth conditions, indicating that the addition sulfur makes the growth processes more favorable for the nucleation and growth of aligned SWNTs.
引用
收藏
页码:3646 / 3650
页数:5
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