Improvement of the mechanical properties of poly(D,L-lactide) by orientation

被引:61
作者
Grijpma, DW
Altpeter, H
Bevis, MJ
Feijen, J
机构
[1] Univ Twente, Fac Chem Technol, Dept Polymer Chem & Biomat, NL-7500 AE Enschede, Netherlands
[2] Univ Twente, Inst Biomed Technol, BMTI, NL-7500 AE Enschede, Netherlands
[3] Brunel Univ, Wolfson Ctr Mat Proc, Uxbridge UB8 3PH, Middx, England
关键词
orientation; poly(D; L-lactide); mechanical properties; degradable polymers;
D O I
10.1002/pi.988
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Oriented, amorphous poly(D,L-lactide) was obtained by drawing injection moulded specimens at temperatures below the glass transition temperature of the polymer and by a non-conventional injection moulding process in which the melt is cooled under oscillating shear conditions (SCORIM). In both cases effective molecular orientation is achieved, allowing the preparation of degradable devices with much improved tensile properties and impact behaviour when compared to the nonoriented material. (C) 2002 Society of Chemical Industry.
引用
收藏
页码:845 / 851
页数:7
相关论文
共 23 条
[1]  
[Anonymous], 1997, STRUCTURE PROPERTIES
[2]  
Benabdillah KM, 1999, MACROMOLECULES, V32, P8774
[3]   FOREIGN-BODY REACTIONS TO RESORBABLE POLY(L-LACTIDE) BONE PLATES AND SCREWS USED FOR THE FIXATION OF UNSTABLE ZYGOMATIC FRACTURES [J].
BERGSMA, EJ ;
ROZEMA, FR ;
BOS, RRM ;
DEBRUIJN, WC .
JOURNAL OF ORAL AND MAXILLOFACIAL SURGERY, 1993, 51 (06) :666-670
[4]   Melt rheology of poly(lactic acid): Entanglement and chain architecture effects [J].
Dorgan, JR ;
Williams, JS ;
Lewis, DN .
JOURNAL OF RHEOLOGY, 1999, 43 (05) :1141-1155
[5]  
Ferguson S, 1996, J BIOMED MATER RES, V30, P543, DOI 10.1002/(SICI)1097-4636(199604)30:4<543::AID-JBM13>3.3.CO
[6]  
2-V
[7]   THE EFFECT OF MELT-PROCESSING ON THE DEGRADATION OF SELECTED POLYHYDROXYACIDS - POLYLACTIDES, POLYHYDROXYBUTYRATE, AND POLYHYDROXYBUTYRATE-CO-VALERATES [J].
GOGOLEWSKI, S ;
JOVANOVIC, M ;
PERREN, SM ;
DILLON, JG ;
HUGHES, MK .
POLYMER DEGRADATION AND STABILITY, 1993, 40 (03) :313-322
[8]   RUBBER TOUGHENING OF POLY(LACTIDE) BY BLENDING AND BLOCK COPOLYMERIZATION [J].
GRIJPMA, DW ;
VANHOFSLOT, RDA ;
SUPER, H ;
NIJENHUIS, AJ ;
PENNINGS, AJ .
POLYMER ENGINEERING AND SCIENCE, 1994, 34 (22) :1674-1684
[9]   (CO)POLYMERS OF L-LACTIDE .2. MECHANICAL-PROPERTIES [J].
GRIJPMA, DW ;
PENNINGS, AJ .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 1994, 195 (05) :1649-1663
[10]   CHAIN ENTANGLEMENT, MECHANICAL-PROPERTIES AND DRAWABILITY OF POLY(LACTIDE) [J].
GRIJPMA, DW ;
PENNING, JP ;
PENNINGS, AJ .
COLLOID AND POLYMER SCIENCE, 1994, 272 (09) :1068-1081