A further application of TPPTS in catalysis: Efficient sucrose-butadiene telomerization using palladium catalysts in water

被引：46

作者：

Pennequin, I ^{[1
]}

Meyer, J ^{[1
]}

Suisse, I ^{[1
]}

Mortreux, A ^{[1
]}

机构：

[1] ENSCL,GRP CHIM ORGAN APPL,URA CNRS 402,CATALYSE HETEROGENE & HOMOGENE LAB,F-69652 VILLEURBANNE,FRANCE

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 120卷 / 1-3期

关键词：

sucrose; butadiene; TPPTS; telomerization;

D O I：

10.1016/S1381-1169(96)00441-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sucrose-butadiene telomerization is efficiently carried out in water or water-organic medium in the presence of a palladium salt and TPPTS (TPPTS = trisodium tris(m-sulfonatophenyl)phosphine as catalyst. Mono- and dioctadienylether compounds are selectively obtained using a NaOH 1 M/isopropanol mixture.

引用

页码：139 / 142

页数：4

共 8 条

[1]

DEKKER M, 1967, NONIONIC SURFACTANTS

[2]

GRUBER B, 1992, Patent No. 42424671

[3]

HECK RF, 1985, PALLADIUM REAGENTS O, P327

[4] PALLADIUM-CATALYZED TELOMERIZATION OF BUTADIENE WITH SUCROSE - A HIGHLY EFFICIENT APPROACH TO NOVEL SUCROSE ETHERS [J].