Ionic liquids and reactive azeotropes: the continuity of the aprotic and protic classes

被引：31

作者：

Canongia Lopes, Jose N. ^{[1
,2
]}

Rebelo, Luis Paulo N. ^{[1
]}

机构：

[1] Univ Nova Lisboa, Inst Tecnol Quim & Biol, P-2780901 Oeiras, Portugal

[2] Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2010年 / 12卷 / 08期

关键词：

D O I：

10.1039/b922524m

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work, we explore the relations between the acid-base reactions implicit in the definition of protic ionic liquids and their solutions, the existence of reactive azeotropy, and the continuity between the aprotic and protic classes of ionic liquids. The profound impact caused by this type of homogenous azeotropy on the fluid phase behaviour (liquid-gas equilibria) of this class of compounds is also discussed.

引用

页码：1948 / 1952

页数：5

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