Nitrogen-carbon bond formation from N2 and CO2 promoted by a hafnocene dinitrogen complex yields a substituted hydrazine

被引：80

作者：

Bernskoetter, Wesley H. ^{[1
]}

Lobkovsky, Emil ^{[1
]}

Chirik, Paul J. ^{[1
]}

机构：

[1] Cornell Univ, Dept Chem & Biol Chem, Ithaca, NY 14853 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 16期

关键词：

carbon dioxide; hafnium; insertion; metallocenes; nitrogen fixation;

D O I：

10.1002/anie.200604099

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Hafnocene and hydrazine: The addition of two equivalents of carbon dioxide to the hafnocene dinitrogen complex 1 proved effective for the formation of nitrogen-carbon bonds directly from N2 and CO2. Subsequent treatment of 2 with Me3Sil liberated the dicarboxylated silyl-substituted hydrazine 3. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2858 / 2861

页数：4

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