Coiled molecules in spring loaded devices

被引：58

作者：

Ajami, Dariush

Rebek, Julius, Jr.

机构：

[1] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

[2] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 47期

关键词：

D O I：

10.1021/ja064233n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cylindrical capsule containing a coiled alkane incorporates spacers. The alkane lengthens and gauche strain is relieved. The spacer can be removed to reset the system to the original state. The system represents a spring-loaded device that operates reversibly in response to acids and bases. Copyright © 2006 American Chemical Society.

引用

收藏

页码：15038 / 15039

页数：2

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