Alkylation of benzene with short-chain olefins over MCM-22 zeolite:: Catalytic behaviour and kinetic mechanism

被引：266

作者：

Corma, A ^{[1
]}

Martínez-Soria, V

Schnoeveld, E

机构：

[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

[2] Univ Valencia, Dept Engn Quim, E-46100 Burjassot, Spain

来源：

JOURNAL OF CATALYSIS | 2000年 / 192卷 / 01期

基金：

欧盟地平线“2020”;

关键词：

benzene alkylation with MCM-22 zeolite; benzene alkylation on Beta zeolite; cumene and ethylbenzene production on; zeolites;

D O I：

10.1006/jcat.2000.2849

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Benzene alkylation with ethene and propene has been carried out under liquid-phase reaction conditions over zeolites MCM-22, Beta, and ZSM-5. MCM-22 seems to be a good catalyst for benzene alkylation especially with propene, showing high activity and stability and good selectivity. Kinetic experiments show that alkylation with propene follows an Eley-Rideal type mechanism. (C) 2000 Academic Press.

引用

页码：163 / 173

页数：11

共 50 条

[1] THE CATALYTIC ISOMERIZATION OF 1-HEXENE ON H-ZSM-5 ZEOLITE - THE EFFECTS OF A SHAPE-SELECTIVE CATALYST
ABBOT, J
CORMA, A
WOJCIECHOWSKI, BW
[J]. JOURNAL OF CATALYSIS, 1985, 92 (02) : 398 - 408
[2] ADAMSON AW, 1997, PHYSICAL CHEM SURFAC
[3] ALLAKHVERDIEVA DT, 1968, NEFTEKHIMIYA, V9, P373
[4] [Anonymous], 1992, ADSORPTION GASES HET, DOI DOI 10.1016/B978-0-12-601690-1.50015-1
[5] [Anonymous], 1991, [No title captured], Patent No. 0432814
[6] BEAUMONT LR, 1992, J AM CHEM SOC, V114, P10834
[7] BENZENE ALKYLATION WITH ETHYLENE AND PROPYLENE OVER H-MORDENITE AS CATALYST
BECKER, KA
KARGE, HG
STREUBEL, WD
[J]. JOURNAL OF CATALYSIS, 1973, 28 (03) : 403 - 413
[8] LIQUID-PHASE ALKYLATION OF BENZENE WITH LIGHT OLEFINS CATALYZED BY BETA-ZEOLITES
BELLUSSI, G
PAZZUCONI, G
PEREGO, C
GIROTTI, G
TERZONI, G
[J]. JOURNAL OF CATALYSIS, 1995, 157 (01) : 227 - 234
[9] Bentham M. F., 1996, P DGMK C CAT SOL AC, P155
[10] BENTHAM MF, 1997, ERDOL ERDGAS KOHLE, V113, P84

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