Precise control of polyolefin stereochemistry using single-site metal catalysts

Single-site catalysts for the stereoselective polymerization of olefins has initiated a revolution in polymer synthesis. Although the vast majority of homogeneous polymerization catalysts are designed for olefin polymerization, the extension of this area of catalysis for the polymerization of other monomers is in progress. The synthesis of homopolymers of stereochemistry from common monomers using tailored single-site catalysts which is a technique that holds great potential for the synthesis of valuable polymers is discussed. New techniques are necessary to allow rapid discovery and optimization of new catalysts, not only stereoselective polymerization catalysts but catalysts in general.