Single-molecule nanomaterials from π-stacked side-chain conjugated polymers

被引:37
作者
Jenekhe, Samson A. [1 ]
Alam, Maksudul M.
Zhu, Yan
Jiang, Shaoyi
Shevade, Abhijit V.
机构
[1] Univ Washington, Dept Chem Engn, Seattle, WA 98195 USA
[2] Univ Washington, Dept Chem, Seattle, WA 98195 USA
[3] Kansas State Univ, Dept Chem Engn, Manhattan, KS 66506 USA
关键词
D O I
10.1002/adma.200601530
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Single-molecule semiconductor nanomaterials with pi-stacked structures in solution and the solid state are prepared from a polystyrene backbone and densely tethered pi-conjugated polyquinoline side chains (see figure). Highly structured optical absorption spectra and exclusive broad, structureless yellow excimer emission in toluene solutions confirm the pi-stacked structures and collective optical properties of the side-chain conjugated polymers.
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页码:536 / +
页数:8
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