Direct measurement of entropic forces induced by rigid rods

被引:79
作者
Helden, L [1 ]
Roth, R
Koenderink, GH
Leiderer, P
Bechinger, C
机构
[1] Univ Konstanz, Dept Phys, D-78457 Constance, Germany
[2] Max Planck Inst Met Res, D-70569 Stuttgart, Germany
[3] Univ Stuttgart, ITAP, D-70569 Stuttgart, Germany
[4] Univ Utrecht, Vant Hoff Lab Phys & Colloid Chem, NL-3584 CH Utrecht, Netherlands
关键词
D O I
10.1103/PhysRevLett.90.048301
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We present the first direct depletion potential measurements for a single colloidal sphere close to a wall in a suspension of rigid colloidal rods. Since all particle interactions are as good as hard-core-like, the depletion potentials are of entirely entropic origin. We developed a density functional theory approach that accurately accounts for this experimental situation. The depletion potentials calculated for different rod number densities are in very good quantitative agreement with the experimental results.
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页数:4
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