A dinuclear iron(III) complex with a bridging urea anion: implications for the urease mechanism

被引：30

作者：

Kryatov, SV

Nazarenko, AY

Robinson, PD

Rybak-Akimova, EV ^{[1
]}

机构：

[1] Tufts Univ, Dept Chem, Medford, MA 02155 USA

[2] So Illinois Univ, Dept Chem & Biochem, Carbondale, IL 62901 USA

[3] So Illinois Univ, Dept Geol, Carbondale, IL 62901 USA

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 11期

关键词：

D O I：

10.1039/b000286k

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

A novel complex [Fe-2(III)(mu-O){mu-OC(NH2)NH}(tpa)(2)](ClO4)(3) [tpa = tris(2-pyridylmethyl)amine] has been synthesized and fully characterized; its formation from urea and the [Fe-2(III)(mu-O)(tpa)(2)(OH)(H2O)](3+) precursor in aqueous acetonitrile is a reversible multistep process.

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收藏

页码：921 / 922

页数：2

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