Synthesis of porphyrins: models of natural hemoproteins and impressive catalysts for asymmetric epoxidation of olefins

被引：61

作者：

Rose, E

Quelquejeu, M

Pandian, RP

Lecas-Nawrocka, A

Vilar, A

Ricart, G

Collman, JP

Wang, Z

Straumanis, A

机构：

[1] Univ Paris 06, UMR 7611, Lab Synth Organ & Organomet, F-75252 Paris 5, France

[2] USTL, Lab Spectrochim Masse, F-59655 Villeneuve Dascq, France

[3] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

来源：

POLYHEDRON | 2000年 / 19卷 / 05期

关键词：

porphyrins; hemoprotein models; chiral catalysts; epoxidation; olefins;

D O I：

10.1016/S0277-5387(99)00413-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Porphyrins, with two chiral binaphthyl handles, efficiently catalyze the epoxidation of terminal olefins to give epoxides with high enantiomeric excess and turnover number. (C) 2000 Elsevier Science Ltd All rights reserved.

引用

页码：581 / 586

页数：6

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