Electron spin echo envelope modulation (ESEEM) spectroscopy as a tool to investigate the coordination environment of metal centers

被引：128

作者：

Deligiannakis, Y

Louloudi, M

Hadjiliadis, N ^{[1
]}

机构：

[1] Univ Ioannina, Dept Chem, Lab Gen & Inorgan Chem, GR-45110 Ioannina, Greece

[2] Natl Ctr Sci Res Demokritos, Inst Mat Sci, Aghia Paraskevi 15310, Greece

来源：

COORDINATION CHEMISTRY REVIEWS | 2000年 / 204卷

关键词：

ESEEM; HYSCORE; metalloproteins; C-13; N-15; O-17;

D O I：

10.1016/S0010-8545(99)00218-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The applications of electron spin echo envelope modulation (ESEEM) spectroscopy to study paramagnetic metal centers in metalloproteins and bioinorganic complexes are reviewed, with special attention to the novel spectroscopic techniques applied and the structural information obtained. We summarize the physical principles and experimental techniques of ESEEM, the spectral shapes and the methods for their analysis. The physical meaning of the spin Hamiltonian parameters is highlighted in conjunction with their utilization for obtaining structural information. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：1 / 112

页数：112

共 351 条

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