An Undecanuclear FeIII Single-Molecule Magnet

被引：72

作者：

Ako, Ayuk M. ^{[1
,2
]}

Mereacre, Valeriu ^{[1
]}

Lan, Yanhua ^{[1
]}

Wernsdorfer, Wolfgang ^{[3
]}

Clerac, Rodolphe ^{[4
,5
]}

Anson, Christopher E. ^{[1
]}

Powell, Annie K. ^{[1
,2
]}

机构：

[1] Univ Karlsruhe, Inst Anorgan Chem, D-76131 Karlsruhe, Germany

[2] Karlsruhe Inst Technol, Inst Nanotechnol, Forschungszentrum Karlsruhe, D-76021 Karlsruhe, Germany

[3] CNRS, Inst Neel, F-38042 Grenoble 9, France

[4] Univ Bordeaux, UPR 8641, F-33600 Pessac, France

[5] CNRS, Ctr Rech Paul Pascal, Equipe Mat Mol Magnet, UPR 8641, F-33600 Pessac, France

来源：

INORGANIC CHEMISTRY | 2010年 / 49卷 / 01期

关键词：

CLUSTERS; IRON(III); COMPLEXES; BEHAVIOR;

D O I：

10.1021/ic901747w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The undecanuclear complex in [Fe-11(III)(mu(4)-O)(3)(mu(3)-O)(4)(L)(3)(mu-O2CCMe3)(12)]Cl center dot 5MeCN has been synthesized and characterized by single-crystal X-ray crystallography. Mossbauer spectroscopy and bulk susceptibility studies reveal that the complex has an S = 13/2 spin ground state and exhibits single-molecule-magnet behavior.

引用

页码：1 / 3

页数：3

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