Synthesis and molecular structure of the unsymmetrically substituted magnesium alkyl Mg(Bun){CH[SPh][SiPh2(CH2NC5H10)]}

被引：11

作者：

Strohmann, C ^{[1
]}

Abele, BC ^{[1
]}

Schildbach, D ^{[1
]}

Strohfeldt, K ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 10期

关键词：

D O I：

10.1039/b000494o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unsymmetrically substituted magnesium alkyl Mg(Bu-n){CH[SPh][SiPh2(CH2NC5H10)]} (NC5H10 = 1-piperidyl) with a stereogenic metalated carbon atom is obtained by deprotonation of an (aminomethyl)[(phenylthio)methyl]silane with (MgBuBus)-Bu-n and examined by single crystal X-ray diffraction analysis and theoretical methods.

引用

页码：865 / 866

页数：2

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