Early transition metal hydride complexes: synthesis and reactivity

被引：105

作者：

Hoskin, AJ ^{[1
]}

Stephan, DW ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

COORDINATION CHEMISTRY REVIEWS | 2002年 / 233卷

关键词：

metal hydride complexes; synthesis; reactivity;

D O I：

10.1016/S0010-8545(02)00030-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review describes the synthesis and reactivity studies of early metal (Sc, Y, Ti, Zr, Hf, V, Nb, Ta) hydride compounds that have appeared over the last 10 years. Every attempt has been made to be comprehensive from 1990 to mid-2001. Complexes reported prior to 1990 have not been discussed. It should also be noted that related subjects that have been recently reviewed including the organic chemistry applications, polyhydride clusters, silica supported Groups 4 and 5 transition metal hydrides and hydride bridged heterobimetallic complexes have been excluded. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：107 / 129

页数：23

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