Advances in non-metallocene olefin polymerization catalysis

被引：2426

作者：

Gibson, VC ^{[1
]}

Spitzmesser, SK ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

CHEMICAL REVIEWS | 2003年 / 103卷 / 01期

关键词：

D O I：

10.1021/cr980461r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The advances in non-metallocene olefin polymerization catalysis were studied. The increasing adoption of high-throughput screening (HTS) methodologies was also discussed. It was found that there were equally significant advances in process design and the engineering of products derived from single-site catalysts.

引用

页码：283 / 315

页数：33

共 568 条

[1] New bis(imino)pyridine-iron(II)- and cobalt(II)-based catalysts:: synthesis characterization and activity towards polymerization of ethylene [J].

Abu-Surrah, AS ;

Lappalainen, K ;

Piironen, U ;

Lehmus, P ;

Repo, T ;

Leskelä, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 648 (1-2) :55-61

[2]

Ahn CH, 2000, MACROMOL RAPID COMM, V21, P385, DOI 10.1002/(SICI)1521-3927(20000401)21:7<385::AID-MARC385>3.0.CO

[3]

2-W

[4] Synthesis of group 4 complexes that contain the tridentate diamido/donor ligands [(ArylNCH2CH2)2O]2- and zirconium complexes that contain [(ArylNCH2CH2)2S]2- and an evaluation of their activity for the polymerization of 1-hexene [J].

Aizenberg, M ;

Turculet, L ;

Davis, WM ;

Schattenmann, F ;

Schrock, RR .

ORGANOMETALLICS, 1998, 17 (22) :4795-4812

[5] Sterically hindered iminophosphorane complexes of vanadium, iron, cobalt and nickel:: a synthetic, structural and catalytic study [J].

Al-Benna, S ;

Sarsfield, MJ ;

Thornton-Pett, M ;

Ormsby, DL ;

Maddox, PJ ;

Brés, P ;

Bochmann, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (23) :4247-4257

[6] Amido functionalized ansa fluorenylidene half-sandwich complexes of zirconium as catalyst precursors for homogeneous ethylene polymerization [J].

Alt, HG ;

Reb, A .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 175 (1-2) :43-50

[7] ω-phenylalkyl substituted amido functionalized ansa half-sandwich complexes of titanium and zirconium and metallacycles thereof as catalyst precursors for homogeneous ethylene polymerization [J].

Alt, HG ;

Reb, A ;

Kundu, K .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 628 (02) :211-221

[8] Amido functionalized ansa half-sandwich dichloride complexes of titanium, zirconium and hafnium with alkyl and ω-alkenyl substituents as homogeneous and self-immobilizing catalyst precursors for ethylene polymerization [J].

Alt, HG ;

Reb, A ;

Milius, W ;

Weis, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 628 (02) :169-182

[9] Synthesis, characterization and polymerization properties of bridged halfsandwich complexes of titanium, Zirconium and Hafnium -: The molecular structure of [C13H8-SiMe2-NtBu]ZrCl2 [J].

Alt, HG ;

Fottinger, K ;

Milius, W .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 572 (01) :21-30

[10] Alkyl complexes of group 4 metals-containing a tridentate-linked amido-cyclopentadienyl ligand: Synthesis, structure, and reactivity including ethylene polymerization catalysis [J].

Amor, F ;

Butt, A ;

du Plooy, KE ;

Spaniol, TP ;

Okuda, J .

ORGANOMETALLICS, 1998, 17 (26) :5836-5849

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