Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area

被引：1331

作者：

Ben, Teng ^{[1
]}

Ren, Hao ^{[1
]}

Ma, Shengqian ^{[2
]}

Cao, Dapeng ^{[3
]}

Lan, Jianhui ^{[3
]}

Jing, Xiaofei ^{[1
]}

Wang, Wenchuan ^{[3
]}

Xu, Jun ^{[4
]}

Deng, Feng ^{[4
]}

Simmons, Jason M. ^{[5
]}

Qiu, Shilun ^{[1
]}

Zhu, Guangshan ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Inorgar Synth & Preparat Chem, Changchun 130023, Peoples R China

[2] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

[3] Beijing Univ Chem Technol, Key Lab Nanomat, Beijing, Peoples R China

[4] Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan, Hubei, Peoples R China

[5] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 50期

关键词：

adsorption; carbon dioxide; hydrogen; organic frameworks; porous materials; COVALENT ORGANIC FRAMEWORKS; MICROPOROUS POLYMERS; HYDROGEN STORAGE; NETWORKS; MIL-100;

D O I：

10.1002/anie.200904637

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Chemical equation presented] Diamonds are forever: A diamond-like framework in which the C-C bonds are replaced with rigid phenyl rings (see picture) is not only structurally stable but also has a large internal surface area. This porous aromatic framework (PAF-1) demonstrates high uptake capacities of hydrogen and carbon dioxide as well as benzene and toluene vapors, and has an unprecedented surface area of 7100 m2 g-1. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9457 / 9460

页数：4

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