Surface-enhanced Raman scattering (SERS) spectra of chloramphenicol in Ag colloids prepared by microwave heating method

被引:22
作者
Si, M. Z. [1 ,2 ]
Kang, Y. P. [3 ]
Zhang, Z. G. [1 ]
机构
[1] Harbin Inst Technol, Dept Phys, Harbin 150080, Peoples R China
[2] Chuxiong Normal Coll, Dept Phys & Elect Sci, Chuxiong 675000, Peoples R China
[3] Yunnan Normal Univ, Dept Phys & Elect Sci, Kunming 650092, Peoples R China
基金
中国国家自然科学基金;
关键词
SERS; Ag colloids; chloramphenicol; microwave heating method; TANDEM MASS-SPECTROMETRY; LIQUID-CHROMATOGRAPHY; GAS-CHROMATOGRAPHY; THIAMPHENICOL; FLORFENICOL; RESIDUES; MUSCLES; MILK; FISH;
D O I
10.1002/jrs.2286
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Ag colloids were prepared by the microwave heating method. The UV-visible spectrum and the transmission electron microscopy (TEM) were employed to characterize the Ag colloids. The surface-enhanced Raman scattering (SERS) spectra of chloramphenicol (CAP) in Ag colloids were successfully recorded. The Raman spectra of CAP were recorded with good concordance comparing to the theoretical results calculated by the Gaussian'98 program. CAP molecules on the Ag surface are oriented tilted to the particle surface via C20-O23, N-O13, and N-O23, which played an important role in the SERS effect. Copyright (C) 2009 John Wiley & Sons, Ltd.
引用
收藏
页码:1319 / 1323
页数:5
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