Structural revision of franchetine and vilmorisine, two norditerpenoid alkaloids from the roots of Aconitum spp.

被引：40

作者：

Wang, FP

Li, ZB

Dai, XP

Peng, CS

机构：

[1] Dept. of Chem. of Med. Nat. Products, School of Pharmacy, West China Univ. of Medical Sciences

来源：

PHYTOCHEMISTRY | 1997年 / 45卷 / 07期

关键词：

Aconitum hemsleyanum var. pengshiese; Ranunculaceae; norditerpenoid alkaloids; franchetine; vilmorisine;

D O I：

10.1016/S0031-9422(97)00164-7

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 [生物化学与分子生物学]; 081704 [应用化学];

摘要：

The structural revision of franchetine (Aconitum franchetii and A. hemsleyanum var. pengshiese) and vilmorisine (A. vilmorinianum) have been carried out on the basis of chemical and H-1, C-13, (HCOSY)-H-1, HETCOR, LOC, 1D-and 2D-NOE NMR spectral studies. They are the novel norditerpenoid alkaloids having a unique mixed N,O-acetal [N-C(17)-O-C(6)] moiety with a Delta 7(8)-double bond. (C) 1997 Elsevier Science Ltd. All rights reserved.

引用

页码：1539 / 1542

页数：4