Stabilization of self-assembled monolayers of carboxylic acids on native oxides of metals

被引：88

作者：

Aronoff, YG ^{[1
]}

Chen, B ^{[1
]}

Lu, G ^{[1
]}

Seto, C ^{[1
]}

Schwartz, J ^{[1
]}

Bernasek, S ^{[1
]}

机构：

[1] PRINCETON UNIV,DEPT CHEM,PRINCETON,NJ 08544

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1997年 / 119卷 / 02期

关键词：

D O I：

10.1021/ja953848+

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Alkanoic acids adsorb weakly to the native oxide surface of aluminum. Treating the oxide surface first with an alkoxide of zirconium provides for strong subsequent adsorption of the alkanoic acid. The formation of an interfacial zirconium carboxylate gives rise to this strong adhesion. A combination of quartz crystal microbalance and ultrahigh-vacuum IR spectroscopic techniques were used to establish the stoichiometry and structural features of the interfacial zirconium carboxylate film.

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页码：259 / 262

页数：4

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