Artificial solid-electrolyte interphase (SEI) for improved cycleability and safety of lithium-ion cells for EV applications

被引:135
作者
Menkin, S. [1 ]
Golodnitsky, D. [1 ,2 ]
Peled, E. [1 ]
机构
[1] Tel Aviv Univ, Sch Chem, IL-69978 Tel Aviv, Israel
[2] Tel Aviv Univ, Wolfson Appl Mat Res Ctr, IL-69978 Tel Aviv, Israel
关键词
Lithium ion battery; SEI; Anode; Safety; Tin; Electric-vehicle; SI NEGATIVE ELECTRODES; BATTERIES; GRAPHITE;
D O I
10.1016/j.elecom.2009.07.019
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Since the SEI is one of the most vulnerable factors in the safety of the lithium-ion battery, improvement in the stability of the SEI will result in a safer battery with better performance characteristics. In this work an artificial SEI was formed on graphite and tin-copper anodes by electropainting and vacuum-insertion techniques. The artificial SEI was found to stabilize the structure of the Sn-Cu anode and led to a cycle life for the cell that was longer by a factor of five and irreversible capacity less than half that of the pristine anode. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1789 / 1791
页数:3
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