New structurally rigid palladium catalysts for the alternating copolymerization of carbon monoxide and ethene

被引：55

作者：

Bianchini, C

Lee, HM

Meli, A

Oberhauser, W

Vizza, F

Brüggeller, P

Rainer, HB

Langes, C

机构：

[1] CNR, Ist Studio Stereochim & Energet Composti Coor, I-50132 Florence, Italy

[2] Univ Innsbruck, Inst Allgemeine Anorgan & Theoret Chem, Innsbruck, Austria

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 09期

关键词：

D O I：

10.1039/b000376j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Decreasing the flexibility of the Ph2PCH2CH2PPh2 (dppe) backbone by making the central carbon atoms part of a cyclobutane ring leads to the formation of Pd( II) catalysts for CO/ethene copolymerization that are more efficient than those of dppe by a factor of ten.

引用

页码：777 / 778

页数：2

共 20 条

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