Instability of [60]fullerene anions in dichloromethane:: a synthetic avenue to C60>(CH2)n methanofullerenes

被引：23

作者：

Beulen, MWJ ^{[1
]}

Echegoyen, L ^{[1
]}

机构：

[1] Univ Miami, Dept Chem, Coral Gables, FL 33124 USA

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 12期

关键词：

D O I：

10.1039/b001021i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The trianion of C-60 reacts readily with the commonly used electrochemical solvent dichloromethane to form methanofullerenes of the type C-60>(CH2)(n), signaling a cautionary warning against the use of this solvent for electrochemical studies of fullerenes and opening up a new synthetic avenue for these adducts.

引用

页码：1065 / 1066

页数：2

共 17 条

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Instability of [60]fullerene anions in dichloromethane:: a synthetic avenue to C60&gt;(CH2)n methanofullerenes

Instability of [60]fullerene anions in dichloromethane:: a synthetic avenue to C60>(CH2)n methanofullerenes