(η6-arene)ruthenium oxomolybdenum and oxotungsten clusters.: Stereochemical non-rigidity of [{Ru(η6-p-MeC6H4Pri)}4Mo4O16] and crystal structure of [{Ru(η6-p-MeC6H4Pri)}4W2O10]

被引：36

作者：

Artero, V ^{[1
]}

Proust, A ^{[1
]}

Herson, P ^{[1
]}

Thouvenot, R ^{[1
]}

Gouzerh, P ^{[1
]}

机构：

[1] Univ Paris 06, Lab Chim Inorgan & Mat Mol, CNRS, Unite 7071, F-75252 Paris 05, France

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 10期

关键词：

D O I：

10.1039/b000782j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

According to a multinuclear NMR study, the cluster [{Ru(eta(6)-p-MeC6H4Pri)}(4)Mo4O16] exists as two isomers, the windmill-like form and the triple-cubane form, which are in equilibrium in solution, while the tungsten analogue, which has been obtained together with the double-cubane type cluster [{Ru(eta(6)-p-MeC6H4Pri)}(4)W2O10] by reaction of [{Ru(eta(6)-p-MeC6H4Pri)Cl-2}(2)] with (NBu4n)(2)[WO4] in acetonitrile, only displays the windmill-like structure.

引用

页码：883 / 884

页数：2

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