Multiple ion cores in anthracene anion clusters

被引：25

作者：

Song, JK ^{[1
]}

Lee, NK ^{[1
]}

Kim, SK ^{[1
]}

机构：

[1] Seoul Natl Univ, Sch Chem, Seoul 151747, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 02期

关键词：

anions; anthracene; density functional; calculations; photoelectron spectroscopy;

D O I：

10.1002/anie.200390081

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spreading the charge: Anion clusters of anthracene, (An)n-, with n values of up to 6 were studied and found to contain a distinctly monomeric, dimeric, or trimeric ion core with a delocalized electronic charge (see figure). Coexistence of dimeric and trimeric ion cores was observed in (An)4-, but the ion core reverts to a monomeric one in (An)5-, with the completion of a solvation shell around the monomer anion.

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页码：213 / +

页数：5

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