Synthesis and photoinduced electron-transfer process of a novel triphenylamine-substituted polyfluorene-C60 triad

The photoinduced electron-transfer process of a newly prepared, soluble, pi-conjugated poly [9,9-bis(4-di-phenylaminophenyl)-2,7-fluorene] (PDPAF), covalently bridged, C-60 triad (C-60-PDPAF-C-60) is described. The molecular orbital calculations revealed that the majority of the highest occupied molecular orbital (HOMO) is located on the polyfluorene entity, while the lowest unoccupied molecular orbitals (LUMO) are found to be entirely on the C-60 entity. The excited-state electron-transfer processes were monitored by both steady-state and time-resolved emission as well as by transient absorption techniques in toluene and benzonitrile. By excitation of the polyfluorene moiety, fluorescence quenching of the singlet excited state of poly-fluorene moiety was observed. The nanosecond transient spectra in near-IR region revealed the charge-separation process from the polyfluorene moieties to the C-60 moiety through the excited singlet states of polyfluorene. The lifetimes of the charge separated states were evaluated to be 20-50 ns, depending on the solvent polarity.