Syntheses of deoxyhexoses from diastereoisomerically pure hetero-Diels-Alder adduct

被引：21

作者：

Bauer, T

机构：

[1] University of Warsaw, Department of Chemistry, Pasteura 1

来源：

TETRAHEDRON | 1997年 / 53卷 / 13期

关键词：

D O I：

10.1016/S0040-4020(97)00159-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Syntheses of deoxyhexoses are presented. The concept is based on the functionalization of enantiomerically pure 6-hydroxymethyl-2-methoxy-5,6-dihydro-2H-pyran, which is easily synthesized by asymmetric hetero-Diels-Alder reaction. Methyl 4,6-dideoxy-alpha-D-arabino-hexopyranoside, methyl alpha-D-chalcoside and methyl alpha-D-desosanimide are synthesized. (C) 1997 Elsevier Science Ltd.

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页码：4763 / 4768

页数：6

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