Novel Lewis acid promoted reactions of allylsilane bearing bulky silyl substituents and aldehydes

被引：21

作者：

Akiyama, T ^{[1
]}

Nakano, M ^{[1
]}

Kanatani, JY ^{[1
]}

Ozaki, S ^{[1
]}

机构：

[1] EHIME UNIV, FAC ENGN, DEPT APPL CHEM, MATSUYAMA, EHIME 790, JAPAN

来源：

CHEMISTRY LETTERS | 1997年 / 04期

关键词：

D O I：

10.1246/cl.1997.385

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reported herein are two novel modes of reactions that were mediated by the proper choice of Lewis acid. Thus, by the influence of SnCl4, allyl-t-butyldimethylsilane reacted with aldehyde in 2:1 stoichiometry to afford a ketone derivative. In contrast, use of BF3 . OEt2 led to the formation of a 1,3-dioxane derivative, which is a 1:2 adduct.

引用

页码：385 / 386

页数：2

共 20 条

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