Spectroscopic and thermodynamic properties of hydrogen bonded water molecules in binary liquid mixtures

被引:20
作者
Bricknell, BC [1 ]
Ford, TA [1 ]
Letcher, TM [1 ]
机构
[1] UNIV NATAL, DEPT CHEM & APPL CHEM, ZA-4041 DURBAN, SOUTH AFRICA
关键词
binary liquid mixtures; spectroscopy; water molecules;
D O I
10.1016/S1386-1425(96)01818-5
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Some relationships have been found between the infrared spectroscopic properties of water molecules hydrogen bonded to a number of bases in binary liquid mixtures, and the partial molar excess enthalpies at infinite dilution of water of the solutions. The results suggest a new approach to the use of the well-known Badger-Bauer relationship. (C) 1997 Elsevier Science B.V.
引用
收藏
页码:299 / 315
页数:17
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