Micro-Raman and infrared properties of SnO2 nanobelts synthesized from Sn and SiO2 powders

Rutile structured SnO2 nanobelts have been synthesized from the mixture of Sri powders and SiO2 nanoparticle powders. Each nanobelt has a uniform width of about several hundred nanometers and a thickness of about tens of nanometers along its entire length. Micro-Raman spectrum measurement on the SnO2 nanobelts shows that the first-order Raman A(1g) mode (632.9 cm(-1)) is very strong, and two weak Raman bands 498 and 694 cm(-1) seem to correspond to infrared (IR)-active longitudinal optical (LO) and transverse optical (TO) of A(2u) modes. In addition, the IR spectrum of the SnO2 nanobelts shows the A(2u) (LO) (701.9 cm(-1)) and E-u(1) (TO) (634.5 cm(-1)) modes and one surface mode (565.2 cm(-1)). The IR-active bands in the Raman spectrum and the surface mode in IR spectrum, which may be due to the nanoscale morphology of the nanobelts. (C) 2003 American Institute of Physics. [DOI: 10.1063/1.1534903].