Evolution of Organic Aerosols in the Atmosphere

被引：2966

作者：

Jimenez, J. L. ^{[1
,2
]}

Canagaratna, M. R. ^{[3
]}

Donahue, N. M. ^{[4
]}

Prevot, A. S. H. ^{[5
]}

Zhang, Q. ^{[6
,7
]}

Kroll, J. H. ^{[3
,8
]}

DeCarlo, P. F. ^{[1
,2
,5
,18
]}

Allan, J. D. ^{[9
,19
]}

Coe, H. ^{[19
]}

Ng, N. L. ^{[3
]}

Aiken, A. C. ^{[1
,2
]}

Docherty, K. S. ^{[1
,2
]}

Ulbrich, I. M. ^{[1
,2
]}

Grieshop, A. P. ^{[4
]}

Robinson, A. L. ^{[4
]}

Duplissy, J. ^{[5
]}

Smith, J. D. ^{[10
]}

Wilson, K. R. ^{[10
]}

Lanz, V. A. ^{[5
,11
]}

Hueglin, C. ^{[11
]}

Sun, Y. L. ^{[6
,7
]}

Tian, J. ^{[6
]}

Laaksonen, A. ^{[12
,13
]}

Raatikainen, T. ^{[12
,13
]}

Rautiainen, J. ^{[12
]}

Vaattovaara, P. ^{[12
]}

Ehn, M. ^{[14
]}

Kulmala, M. ^{[14
,15
]}

Tomlinson, J. M. ^{[16
]}

Collins, D. R. ^{[16
]}

Cubison, M. J. ^{[1
,2
]}

Dunlea, E. J. ^{[1
,2
]}

Huffman, J. A. ^{[1
,2
]}

Onasch, T. B. ^{[3
]}

Alfarra, M. R. ^{[5
,9
,19
]}

Williams, P. I. ^{[9
,19
]}

Bower, K. ^{[9
,19
]}

Kondo, Y. ^{[17
]}

Schneider, J. ^{[20
]}

Drewnick, F. ^{[6
,20
]}

Borrmann, S. ^{[20
,21
]}

Weimer, S. ^{[5
,6
,22
]}

Demerjian, K. ^{[6
]}

Salcedo, D. ^{[23
]}

Cottrell, L. ^{[24
]}

Griffin, R. ^{[24
,25
]}

Takami, A. ^{[26
]}

Miyoshi, T. ^{[26
]}

Hatakeyama, S. ^{[26
]}

Shimono, A. ^{[27
]}

机构：

[1] Univ Colorado, Cooperat Inst Res Environm Sci, Boulder, CO 80309 USA

[2] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

[3] Aerodyne Res Inc, Billerica, MA 01821 USA

[4] Carnegie Mellon Univ, Ctr Atmospher Particle Studies, Pittsburgh, PA 15213 USA

[5] Paul Scherrer Inst, Lab Atmospher Chem, Villigen, Switzerland

[6] SUNY Albany, Atmospher Sci Res Ctr, Albany, NY 12222 USA

[7] Univ Calif Davis, Dept Environm Toxicol, Davis, CA 95616 USA

[8] MIT, Dept Civil & Environm Engn, Cambridge, MA 02139 USA

[9] Univ Manchester, Natl Ctr Atmospher Sci, Manchester, Lancs, England

[10] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA

[11] Empa, Lab Air Pollut Environm Technol, Dubendorf, Switzerland

[12] Univ Kuopio, Dept Phys, FIN-70211 Kuopio, Finland

[13] Finnish Meteorol Inst, FIN-00101 Helsinki, Finland

[14] Univ Helsinki, Dept Phys, Helsinki, Finland

[15] Stockholm Univ, Dept Appl Environm Sci, S-10691 Stockholm, Sweden

[16] Texas A&M Univ, Dept Atmospher Sci, College Stn, TX USA

[17] Univ Tokyo, Adv Sci & Technol Res Ctr, Tokyo, Japan

[18] Univ Colorado, Dept Atmospher & Ocean Sci, Boulder, CO 80309 USA

[19] Univ Manchester, Sch Earth Atmospher & Environm Sci, Manchester, Lancs, England

[20] Max Planck Inst Chem, Dept Particle Chem, D-55128 Mainz, Germany

[21] Johannes Gutenberg Univ Mainz, Inst Atmospher Phys, Mainz, Germany

[22] Empa, Lab Internal Combust Engines, Dubendorf, Switzerland

[23] Univ Autonoma Estado Morelos, Ctr Invest Quim, Cuernavaca, Morelos, Mexico

[24] Univ New Hampshire, Climate Change Res Ctr, Durham, NH 03824 USA

[25] Rice Univ, Dept Civil & Environm Engn, Houston, TX USA

[26] Natl Inst Environm Studies, Asian Environm Res Grp, Tsukuba, Ibaraki, Japan

[27] Sanyu Plant Serv, Sagamihara, Kanagawa, Japan

[28] Chinese Acad Meteorol Sci, Key Lab Atmospher Chem, Beijing, Peoples R China

[29] Natl Ctr Atmospher Res, Div Atmospher Chem, Boulder, CO 80307 USA

[30] Tofwerk, Thun, Switzerland

[31] NOAA, Earth Sci Res Lab, Boulder, CO USA

来源：

SCIENCE | 2009年 / 326卷 / 5959期

基金：

美国国家科学基金会; 美国海洋和大气管理局;

关键词：

SECONDARY; MASS; PITTSBURGH; CHEMISTRY; EMISSIONS; OXIDATION; GROWTH; MODEL;

D O I：

10.1126/science.1180353

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Organic aerosol (OA) particles affect climate forcing and human health, but their sources and evolution remain poorly characterized. We present a unifying model framework describing the atmospheric evolution of OA that is constrained by high-time-resolution measurements of its composition, volatility, and oxidation state. OA and OA precursor gases evolve by becoming increasingly oxidized, less volatile, and more hygroscopic, leading to the formation of oxygenated organic aerosol (OOA), with concentrations comparable to those of sulfate aerosol throughout the Northern Hemisphere. Our model framework captures the dynamic aging behavior observed in both the atmosphere and laboratory: It can serve as a basis for improving parameterizations in regional and global models.

引用

页码：1525 / 1529

页数：5

共 31 条

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