Origins of unsaturation in group 6 metallaboranes. Synthesis, crystal structure, and molecular orbital calculations for (CpMoCl)(2)B3H7 (Cp = pentamethylcyclopentadienyl)

被引：19

作者：

Aldridge, S ^{[1
]}

Shang, MY ^{[1
]}

Fehlner, TP ^{[1
]}

机构：

[1] UNIV NOTRE DAME,DEPT CHEM & BIOCHEM,NOTRE DAME,IN 46556

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1997年 / 119卷 / 45期

关键词：

D O I：

10.1021/ja972685h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：11120 / 11121

页数：2

共 21 条

[1] FACILE ACTIVATION OF HYDROGEN BY AN UNSATURATED METAL-CARBONYL CLUSTER - THE ADDITION OF H-2 TO OS4(CO)11(MU-4-S)(MU-4-HC2CO2ME) [J].

ADAMS, RD ;

WANG, S .

ORGANOMETALLICS, 1986, 5 (06) :1272-1274

[2] LIGAND-ASSISTED ADDITION-REACTIONS .1. ALKYNE ADDITIONS AND COUPLINGS IN THE UNSATURATED CLUSTER COMPLEXES OS4(CO)11(MU-4-RC2CO2ME)(MU-4-S) (R = H AND CO2ME) [J].

ADAMS, RD ;

WANG, S .

ORGANOMETALLICS, 1987, 6 (04) :739-748

[3] Directed synthesis of chromium and molybdenum metallaborane clusters. Preparation and characterization of (Cp*Cr)(2)B5H9, (Cp*Mo)(2)B5H9, and (Cp*MoCl)(2)B4H10 [J].

Aldridge, S ;

Fehlner, TP ;

Shang, MY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (09) :2339-2340

[4] SYNTHESIS OF ETA-CYCLOPENTADIENYL-POLYBORANE DERIVATIVES OF MOLYBDENUM AND TUNGSTEN [J].

BULLICK, HJ ;

GREBENIK, PD ;

GREEN, MLH ;

HUGHES, AK ;

LEACH, JB ;

MCGOWAN, PC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (01) :67-75

[5] MOLYBDENUM-TO-MOLYBDENUM TRIPLE BOND .5. PREPARATION AND STRUCTURE OF DIMETHYLTETRAKIS(DIMETHYLAMIDO)DIMOLYBDENUM [J].

CHISHOLM, MH ;

COTTON, FA ;

EXTINE, MW ;

MURILLO, CA .

INORGANIC CHEMISTRY, 1978, 17 (08) :2338-2340

[6] PREPARATION AND STRUCTURE OF (CP-ASTERISK-CR)(2)B4H8 - AN UNSATURATED METALLABORANE CLUSTER WITH AN UNEXPECTED STRUCTURE [J].

DECK, KJ ;

NISHIHARA, Y ;

SHANG, M ;

FEHLNER, TP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (18) :8408-8409

[7] CRYSTAL AND MOLECULAR-STRUCTURE OF TRI-MU-CHLORO-BIS[DICARBONYLBIS(TRIMETHYL PHOSPHITE)MOLYBDENUM] TETRACHLORO(DIMETHYL PHOSPHITO)OXOMOLYBDATE [J].

DREW, MGB ;

WILKINS, JD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (20) :1984-1989

[8]

FEHLNER TP, IN PRESS J ORGANOMET

[9]

Fenske R.F., 1988, PURE APPL CHEM, V27, P61

[10] QUADRUPLY BONDED TETRAMETHYLTETRAKIS(TRIALKYLPHOSPHINE)DIMOLYBDENUM COMPOUNDS - PHOSPHINE EXCHANGE KINETICS, ACETONE FORMATION WITH CARBON-MONOXIDE, AND CRYSTAL-STRUCTURE OF MO2ME4(PME3)4 [J].

GIROLAMI, GS ;

MAINZ, VV ;

ANDERSEN, RA ;

VOLLMER, SH ;

DAY, VW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (13) :3953-3955

← 1 2 3 →

Origins of unsaturation in group 6 metallaboranes. Synthesis, crystal structure, and molecular orbital calculations for (Cp*MoCl)(2)B3H7 (Cp* = pentamethylcyclopentadienyl)

Origins of unsaturation in group 6 metallaboranes. Synthesis, crystal structure, and molecular orbital calculations for (CpMoCl)(2)B3H7 (Cp = pentamethylcyclopentadienyl)