Cs+-selective ion exchange and magnetic ordering in a three-dimensional framework uranyl vanadium(IV) phosphate

被引：69

作者：

Shvareva, Tatiana Y.

Skanthakumar, S.

Soderholm, L.

Clearfield, Abraham

Albrecht-Schmitt, Thomas E. ^{[1
]}

机构：

[1] Auburn Univ, Dept Chem & Biochem, Auburn, AL 36849 USA

[2] Auburn Univ, EC Leach Nucl Sci Ctr, Auburn, AL 36849 USA

[3] Argonne Natl Lab, Div Chem, Argonne, IL 60439 USA

[4] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

CHEMISTRY OF MATERIALS | 2007年 / 19卷 / 02期

关键词：

D O I：

10.1021/cm062490l

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cs+- selective ion exchange and magnetic ordering in a three-dimensional framework uranyl vanadium (IV) phosphate was studied. The synthesis of K [(UO2)(VO)4H1.52(PO 4)5] was achieved by reacting UO2(NO 3)2.6H2O with V metal phosphoric acid, and KCI under mild conditions. Confirmation of the +4 oxidation state for vanadium was provided by magnetic susceptibility measurements on Rb-UVP-2. This work provides further expansion of the structural building units that can be used to construct three-dimensional uranyl containing frameworks.

引用

页码：132 / 134

页数：3

共 25 条

[1] BOND-VALENCE PARAMETERS FOR SOLIDS [J].