High-pressure phases and structural bonding of Ge3N4

被引：33

作者：

Lowther, JE ^{[1
]}

机构：

[1] Univ Witwatersrand, Dept Phys, Johannesburg, South Africa

来源：

PHYSICAL REVIEW B | 2000年 / 62卷 / 01期

关键词：

D O I：

10.1103/PhysRevB.62.5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The spinel structure of Ge3N4 is compared with that of beta-Ge3N4 and a cubic defect zinc-blende structure recently considered possible for C3N4. The beta phase is suggested to be a possible precursor phase to the spinel structure. Electronic structure calculations reveal that the spinel structure is a subtle extension of the defect zinc-blende phase in which the Ge atoms attempt to connect into the conventional zinc-blends structure.

引用

页码：5 / 8

页数：4

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