Synthesis and aggregates of phenylene-ethynylene substituted polycyclic aromatic compounds

被引:13
作者
Cheng, XH
Jester, SS
Höger, S
机构
[1] Inst Tech Chem & Polymerchem, D-79131 Karlsruhe, Germany
[2] Inst Chem Phys, D-76131 Karlsruhe, Germany
关键词
D O I
10.1021/ma048728d
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis of polycyclic aromatic compounds and the aggregation of compounds in solutions were analyzed. The polycyclic aromatics that were capable of undergoing C-C coupling reactions were synthesized in a two step route. These compounds were found to be used as building blocks for complex molecular architecture, such as phenylene-ethnylenes. The concentration-dependent nuclear magnetic resonance (NMR) experiments determined that these compounds aggregated in the solution and this helped in the identification of solid substrates on different superstructures.
引用
收藏
页码:7065 / 7068
页数:4
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