Synthesis and structural characterisation of two- and three-dimensional fluorinated indium phosphates

被引：27

作者：

Du, HB

Chen, JS

Pang, WQ

Yu, JH

Williams, ID

机构：

[1] JILIN UNIV,DEPT CHEM,KEY LAB INORGAN HYDROTHERMAL SYNTH,CHANGCHUN 130023,PEOPLES R CHINA

[2] HONG KONG UNIV SCI & TECHNOL,DEPT CHEM,KOWLOON,HONG KONG

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 08期

关键词：

D O I：

10.1039/a700775b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrothermal synthesis of two new fluorinated indium phosphates [InPO4F(Hen)] and [In5P4F3O16(en)(3)(OH2)(2)] is carried out in the system In2O3-P2O5-en-HF-H2O (en = ethylenediamine); these have two- and three-dimensional inorganic frameworks respectively, with the latter having ten-membered ring channels spanned by coordinated en; the fluorides bridge exclusively between indium ions and may be linear or bent.

引用

页码：781 / 782

页数：2

共 20 条

[1]

BARRER RM, 1982, HYDROTHERMAL CHEM ZE, P44

[2]

CASCI JL, 1994, STUD SURF SCI CATAL, V85, P329

[3]

CCHIPPINDALE AM, 1996, CHEM COMMUN, P2781

[4] Novel pillared layer structure of the organically templated indium phosphate [In-8(HPO4)(14)(H2O)(6)](H2O)(5)(H3O)(C3N2H5)(3) [J].