Effect of adsorbed polyaniline on the thermal stability of iron and arsenic oxides

被引:4
作者
de Farias, RF [1 ]
机构
[1] Univ Fed Roraima, UFRR, Dept Quim, BR-69310270 Boa Vista, RO, Brazil
来源
QUIMICA NOVA | 2000年 / 23卷 / 03期
关键词
polyaniline; thermal degradation; oxide;
D O I
10.1590/S0100-40422000000300006
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Iron and arsenic oxide grains are coated with the conducting organic polymer polyaniline. The obtained samples mere characterized by infrared spectroscopy, SEM, conducting measurements and thermogravimetry. The thermal stability of both oxides are increased. For As2O3 the sublimation temperature is increased from 165 degrees C in the pure oxide to 206 degrees C in the polymer modified sample. The pure Fe3O4 sample exhibits sublimation at 780 degrees C whereas the polyaniline coated oxide is stable until at least 1000 degrees C.
引用
收藏
页码:313 / 315
页数:3
相关论文
共 34 条
  • [1] BISSESSUR R, 1993, J CHEM SOC CHEM COMM, P688
  • [2] BONNET B, 1992, MATER SCI FORUM, V91, P177
  • [3] THERMAL-ANALYSIS OF CONDUCTING POLYMERS .1. THERMOGRAVIMETRY OF ACID-DOPED POLYANILINES
    CHAN, HSO
    TEO, MYB
    KHOR, E
    LIM, CN
    [J]. JOURNAL OF THERMAL ANALYSIS, 1989, 35 (03): : 765 - 774
  • [4] Effects of adsorbed polyaniline on redox process on MoO3 surface
    de Farias, RF
    de Souza, JM
    de Melo, JV
    Airoldi, C
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1999, 212 (01) : 123 - 129
  • [5] Thermogravimetry as a reliable tool to estimate the density of silanols on a silica gel surface
    de Farias, RF
    Airoldi, C
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 1998, 53 (03): : 751 - 756
  • [6] DEFARIAS RF, 2000, IN PRESS J COLLOID I
  • [7] DEFARIAS RF, 2000, IN PRESS J THERMAL A
  • [8] ASSEMBLY AND POLYMERIZATION OF SOME AROMATIC-AMINES IN ALPHA-VOPO4-CENTER-DOT-2H(2)O
    DESTEFANIS, A
    FOGLIA, S
    TOMLINSON, AAG
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (03) : 475 - 483
  • [9] BIOMASS PHOTOCHEMISTRY .15. PHOTOBLEACHING AND BIOBLEACHING OF KRAFT EFFLUENT
    DURAN, N
    DEZOTTI, M
    RODRIGUEZ, J
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1991, 62 (02) : 269 - 279
  • [10] Duran Nelson, 1994, Biodegradation, V5, P13