Subatmospheric vapor pressure curves for propionic acid, butyric acid, isobutyric acid, valeric acid, isovaleric acid, hexanoic acid, and heptanoic acid

被引:28
作者
Clifford, SL [1 ]
Ramjugernath, D [1 ]
Raal, JD [1 ]
机构
[1] Univ Natal, Thermodynam Res Unit, Sch Chem Engn, ZA-4041 Durban, South Africa
关键词
D O I
10.1021/je034180e
中图分类号
O414.1 [热力学];
学科分类号
摘要
Vapor pressure data were measured for the following carboxylic acids: propionic, butyric, isobutyric, valeric, isovaleric, hexanoic, and heptanoic acids. The pressure ranged between similar to5 kPa and atmospheric pressure (at sea level), and the corresponding temperatures were between 85 and 180 degreesC, depending on the acid being measured. The data were regressed using both the Antoine and Wagner equations, and the parameters obtained for each equation are presented. The experimental data were also compared to literature data, and the results are discussed.
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页码:1189 / 1192
页数:4
相关论文
共 14 条
[1]   VAPOR-PRESSURES AND CRITICAL-TEMPERATURES AND CRITICAL PRESSURES OF SOME ALKANOIC ACIDS - C-1 TO C-10 [J].
AMBROSE, D ;
GHIASSEE, NB .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1987, 19 (05) :505-519
[2]   VAPOR PRESSURE TEMPERATURE DATA ON SOME ORGANIC COMPOUNDS [J].
DREISBACH, RR ;
SHRADER, SA .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1949, 41 (12) :2879-2880
[3]   THE VAPOR PRESSURE OF MONOFLUOROACETIC ACID [J].
JASPER, JJ ;
MILLER, GB .
JOURNAL OF PHYSICAL CHEMISTRY, 1955, 59 (05) :441-442
[4]  
JOSEPH M, 2001, THESIS U NATAL DURBA
[5]   Phase equilibrium properties of binary systems with diacetyl from a computer controlled vapour-liquid equilibrium still [J].
Joseph, MA ;
Raal, JD ;
Ramjugernath, D .
FLUID PHASE EQUILIBRIA, 2001, 182 (1-2) :157-176
[6]   Isobaric vapor liquid equilibrium (VLE) data of the systems n-butanol plus butyric acid and n-butanol plus acetic acid [J].
Muñoz, LAL ;
Krähenbühl, MA .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2001, 46 (01) :120-124
[7]   Boiling points of n-alkyl acids [J].
Pool, WO ;
Ralston, AW .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1942, 34 :1104-1105
[8]  
Prausnitz J., 1980, COMPUTER CALCULATION
[9]  
Raal J.D., 1998, Phase Equilibria: Measurement Computation
[10]  
Reid C., 1988, PROPERTIES GASES LIQ