A novel nonacoordinate bridging selenido ligand in a tricapped trigonal-prismatic geometry.: X-Ray structure of Cu11(μ9-Se)(μ3-Br)3[Se2P(OPri)2]6

被引：42

作者：

Liu, CW ^{[1
]}

Hung, CM

Chen, HC

Wang, JC

Keng, TC

Guo, K

机构：

[1] Chung Yuan Christian Univ, Dept Chem, Chungli 320, Taiwan

[2] Soochow Univ, Dept Chem, Taipei 111, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 19期

关键词：

D O I：

10.1039/b005366j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first nonacoordinate bridging selenido ligand in a tricapped trigonal prismatic geometry, Cu-11(mu(9)-Se)(mu(3)-Br)(3)[Se2P(OPri)(2)](6), is prepared along with closed-shell ion-centered Cu-8(I) cubes, Cu-8(mu(8)-Se)[Se2P(OPri)(2)](6) and Cu-8(mu(8)-Br)[Se2P(OPri)(2)](6)(PF6), from the reaction of NH4Se2P(OPri)(2), Cu(CH3CN)(4)PF6, and Bu4NBr in CH2Br2 at 0 degrees C.

引用

页码：1897 / 1898

页数：2

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