Stereocontrolled cyclopropanation of Garner's aldehyde derived enones

被引：19

作者：

Ma, DW

Jiang, YW

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China

[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 18期

关键词：

D O I：

10.1016/S0957-4166(00)00327-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of sulfonium ylides with enones 5 derived from (S)-Garner's aldehyde in toluene provides 1,2,3-trisubstituted cyclopropanes. The configuration of the major isomer is 2R,1'R,2'R,3'R. Using this reaction a 3-benzyl analogue of the CCG family compounds was synthesized. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：3727 / 3736

页数：10

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